Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex

[Image: see text] To obtain mechanistic insights into the inherent reactivity patterns for copper(I)–O(2) adducts, a new cupric–superoxo complex [(DMM-tmpa)Cu(II)(O(2)(•–))](+) (2) [DMM-tmpa = tris((4-methoxy-3,5-dimethylpyridin-2-yl)methyl)amine] has been synthesized and studied in phenol oxidation...

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Detalhes bibliográficos
Principais autores: Lee, Jung Yoon, Peterson, Ryan L., Ohkubo, Kei, Garcia-Bosch, Isaac, Himes, Richard A., Woertink, Julia, Moore, Cathy D., Solomon, Edward I., Fukuzumi, Shunichi, Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4102632/
https://ncbi.nlm.nih.gov/pubmed/24953129
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja503105b
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