A Selective Stepwise Heme Oxygenase Model System: An Iron(IV)-Oxo Porphyrin π-Cation Radical Leads to a Verdoheme-Type Compound via an Isoporphyrin Intermediate

Por Garcia-Bosch, Isaac, Sharma, Savita, Karlin, Kenneth D.
Publicado em 2013

Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides

Por Hematian, Shabnam, Garcia-Bosch, Isaac, Karlin, Kenneth D.
Publicado no Acc Chem Res (2015)

Substrate and Lewis Acid Coordination Promote O–O Bond Cleavage of an Unreactive L(2)Cu(II)(2)(O(2)(2−)) Species to Form L(2)Cu(III)(2)(O)(2) Cores with Enhanced Oxidative Reactivi...

Por Garcia-Bosch, Isaac, Cowley, Ryan E., Díaz, Daniel E., Peterson, Ryan L., Solomon, Edward I., Karlin, Kenneth D.
Publicado no J Am Chem Soc (2017)

Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu(2)O(2) Core with Unexpected Structure and Reactivity

Por Garcia-Bosch, Isaac, Cowley, Ryan E., Díaz, Daniel E., Siegler, Maxime A., Nam, Wonwoo, Solomon, Edward I., Karlin, Kenneth D.
Publicado no Chemistry (2016)

A “Naked” Fe(III)-(O(2)(2–))-Cu(II) Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes

Por Garcia-Bosch, Isaac, Adam, Suzanne M., Schaefer, Andrew W., Sharma, Savita K., Peterson, Ryan L., Solomon, Edward I., Karlin, Kenneth D.
Publicado no J Am Chem Soc (2015)

Critical Aspects of Heme–Peroxo–Cu Complex Structure and Nature of Proton Source Dictate Metal–O(peroxo) Breakage versus Reductive O–O Cleavage Chemistry

Por Adam, Suzanne M., Garcia-Bosch, Isaac, Schaefer, Andrew W., Sharma, Savita K., Siegler, Maxime A., Solomon, Edward I., Karlin, Kenneth D.
Publicado no J Am Chem Soc (2016)

Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex

Por Lee, Jung Yoon, Peterson, Ryan L., Ohkubo, Kei, Garcia-Bosch, Isaac, Himes, Richard A., Woertink, Julia, Moore, Cathy D., Solomon, Edward I., Fukuzumi, Shunichi, Karlin, Kenneth D.
Publicado em 2014

O(2) Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper μ-η(1):η(1)-Peroxido Complex()

Por Garcia-Bosch, Isaac, Company, Anna, Frisch, Jonathan R., Torrent-Sucarrat, Miquel, Cardellach, Mar, Gamba, Ilaria, Güell, Mireia, Casella, Luigi, Que, Lawrence, Ribas, Xavi, Luis, Josep M., Costas, Miquel
Publicado em 2010