Caricamento...
A Selective Stepwise Heme Oxygenase Model System: An Iron(IV)-Oxo Porphyrin π-Cation Radical Leads to a Verdoheme-Type Compound via an Isoporphyrin Intermediate
The selective oxidation of the α-position of two heme-Fe(III) tetraarylporphryinate complexes occurs when water( hydroxide) attacks their oxidized Cmpd I-type equivalents, highvalent Fe(IV)=O π-cation-radical species ((P(+•))Fe(IV)=O). Stepwise intermediate formation occurs, as detected by UV-vis sp...
Salvato in:
| Autori principali: | , , |
|---|---|
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
|
| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3877574/ https://ncbi.nlm.nih.gov/pubmed/24147457 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405739m |
| Tags: |
Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !
|