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Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu(2)O(2) Core with Unexpected Structure and Reactivity
We report the Cu(I)/O(2) chemistry of complexes derived from the macrocylic ligands 14-TMC (1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and 12-TMC (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane). While [(14-TMC)Cu(I)](+) is unreactive towards dioxygen, the smaller analog [(12-TMC)C...
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| izdano v: | Chemistry |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4852750/ https://ncbi.nlm.nih.gov/pubmed/26919169 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600551 |
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