Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu(2)O(2) Core with Unexpected Structure and Reactivity

We report the Cu(I)/O(2) chemistry of complexes derived from the macrocylic ligands 14-TMC (1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and 12-TMC (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane). While [(14-TMC)Cu(I)](+) is unreactive towards dioxygen, the smaller analog [(12-TMC)C...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Garcia-Bosch, Isaac, Cowley, Ryan E., Díaz, Daniel E., Siegler, Maxime A., Nam, Wonwoo, Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4852750/
https://ncbi.nlm.nih.gov/pubmed/26919169
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600551
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!

Registos relacionados