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Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu(2)O(2) Core with Unexpected Structure and Reactivity

We report the Cu(I)/O(2) chemistry of complexes derived from the macrocylic ligands 14-TMC (1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and 12-TMC (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane). While [(14-TMC)Cu(I)](+) is unreactive towards dioxygen, the smaller analog [(12-TMC)C...

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Bibliografske podrobnosti
izdano v:Chemistry
Main Authors: Garcia-Bosch, Isaac, Cowley, Ryan E., Díaz, Daniel E., Siegler, Maxime A., Nam, Wonwoo, Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Jezik:Inglês
Izdano: 2016
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4852750/
https://ncbi.nlm.nih.gov/pubmed/26919169
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600551
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