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Coordination Chemistry and Reactivity of a Cupric-hydroperoxide Species Featuring a Proximal H-bonding Substituent
At −90 °C in acetone, a stable hydroperoxo complex [(BA)Cu(II)-OOH](+) (2) (BA, a tetradentate N(4) ligand possessing a pendant –N(H)CH(2)C(6)H(5) group) is generated by reacting [(BA)Cu(II)(CH(3)COCH(3))](2+) with only one equiv H(2)O(2)/Et(3)N. The exceptional stability of 2 is ascribed to interna...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3513638/ https://ncbi.nlm.nih.gov/pubmed/23153187 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic302071e |
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