Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O–H and C–H Substrates

Dioxygen reactivity of a series of TMPA-based copper(I) complexes (TMPA ≡ tris(2-pyridylmethyl)amine), with and without secondary coordination sphere hydrogen-bonding moieties, were studied at −135 °C in 2-methyltetrahydrofuran (MeTHF). Kinetic stabilization of H-bonded [(((X1)(X2))TMPA)Cu(II)(O(2)(...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Diaz, Daniel E., Quist, David A., Herzog, Austin E., Schaefer, Andrew W., Kipouros, Ioannis, Bhadra, Mayukh, Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6878127/
https://ncbi.nlm.nih.gov/pubmed/31469942
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908471
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