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Copper/α-Ketocarboxylate Chemistry With Supporting Peralkyated Diamines: Reactivity of Copper(I) Complexes and Dicopper-Oxygen Intermediates
To further understand copper-promoted oxidation reactions, the Cu(I) complexes LCuX (L = N,N-di-tert-butyl-N′,N′-dimethylethylenediamine; X = benzoylformate (BF) or p-nitro-benzoylformate) were synthesized, fully characterized by X-ray crystallography and spectroscopy in solution, and their reactivi...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2010
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2878206/ https://ncbi.nlm.nih.gov/pubmed/20218646 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic100032n |
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