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Intermediates in Reactions of Copper(I) Complexes with N-Oxides: From Formation of Stable Adducts to Oxo Transfer

Reactions of Cu(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel Cu(I)-N-oxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving...

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Bibliografiske detaljer
Main Authors: Hong, Sungjun, Gupta, Aalo K., Tolman, William B.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2878392/
https://ncbi.nlm.nih.gov/pubmed/19425587
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic900435p
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