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Mechanistic Insight into Oxygen Atom Transfer Reactions by Mononuclear Manganese(IV)-oxo Adducts

High-valent metal-oxo intermediates are well known to facilitate oxygen-atom transfer (OAT) reactions both in biological and synthetic systems. These reactions can occur by a single-step OAT mechanism or by a stepwise process initiated by rate-limiting electron transfer between the substrate and the...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Singh, Priya, Stewart-Jones, Eleanor, Denler, Melissa C., Jackson, Timothy A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8075156/
https://ncbi.nlm.nih.gov/pubmed/33616141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0dt04436a
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