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Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions
A mononuclear Cr(v)–oxo complex, [Cr(V)(O)(6-COO(–)-tpa)](BF(4))(2) (1; 6-COO(–)-tpa = N,N-bis(2-pyridylmethyl)-N-(6-carboxylato-2-pyridylmethyl)amine) was prepared through the reaction of a Cr(iii) precursor complex with iodosylbenzene as an oxidant. Characterization of 1 was achieved using ESI-MS...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811151/ https://ncbi.nlm.nih.gov/pubmed/29560181 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02285h |
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