Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

A mononuclear Cr(v)–oxo complex, [Cr(V)(O)(6-COO(–)-tpa)](BF(4))(2) (1; 6-COO(–)-tpa = N,N-bis(2-pyridylmethyl)-N-(6-carboxylato-2-pyridylmethyl)amine) was prepared through the reaction of a Cr(iii) precursor complex with iodosylbenzene as an oxidant. Characterization of 1 was achieved using ESI-MS...

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Vydáno v:Chem Sci
Hlavní autoři: Kotani, Hiroaki, Kaida, Suzue, Ishizuka, Tomoya, Sakaguchi, Miyuki, Ogura, Takashi, Shiota, Yoshihito, Yoshizawa, Kazunari, Kojima, Takahiko
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2015
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811151/
https://ncbi.nlm.nih.gov/pubmed/29560181
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02285h
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