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Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

There has been considerable interest in hydrogen atom transfer (HAT) reactions mediated by metal/oxygen species because of their central role in metalloenzyme function as well as synthetic catalysts. This Account focuses on our progress in synthesizing high-valent metal–oxo and metal–hydroxo porphyr...

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Detalhes bibliográficos
Publicado no:Acc Chem Res
Main Authors: Sacramento, Jireh Joy D., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6676912/
https://ncbi.nlm.nih.gov/pubmed/30403479
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.8b00414
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