Dramatic Influence of an Anionic Donor on the Oxygen-Atom Transfer Reactivity of a Mn(V)–Oxo Complex

Addition of an anionic donor to an Mn(V)(O) porphyrinoid complex causes a dramatic increase in 2-electron oxygen-atom-transfer (OAT) chemistry. The 6-coordinate [Mn(V)(O)(TBP(8)Cz)(CN)](−) was generated from addition of Bu(4)N(+)CN(−) to the 5-coordinate Mn(V)(O) precursor. The cyanide-ligated compl...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Neu, Heather M, Quesne, Matthew G, Yang, Tzuhsiung, Prokop-Prigge, Katharine A, Lancaster, Kyle M, Donohoe, James, DeBeer, Serena, de Visser, Sam P, Goldberg, David P
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
Assuntos:
Communication
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4321347/
https://ncbi.nlm.nih.gov/pubmed/25256417
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201404349
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