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Singlet versus Triplet Reactivity in an Mn(V)–Oxo Species: Testing Theoretical Predictions Against Experimental Evidence
Discerning the factors that control the reactivity of high-valent metal–oxo species is critical to both an understanding of metalloenzyme reactivity and related transition metal catalysts. Computational studies have suggested that an excited higher spin state in a number of metal–oxo species can pro...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5228574/ https://ncbi.nlm.nih.gov/pubmed/27545752 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b05027 |
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