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A Balancing Act: Stability versus Reactivity of Mn(O) Complexes
A large class of heme and nonheme metalloenzymes utilize O(2) or its derivatives (e.g. H(2)O(2)) to generate high-valent metal-oxo intermediates for performing challenging and selective oxidations. Due to their reactive nature, these intermediates are often short-lived and very difficult to characte...
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| Publicado no: | Acc Chem Res |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4873303/ https://ncbi.nlm.nih.gov/pubmed/26352344 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00273 |
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