Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres

[Image: see text] The new ligand N3Py(amide)SR and its Fe(II) complex [Fe(II)(N3Py(amide)SR)](BF(4))(2) (1) are described. Reaction of 1 with PhIO at −40 °C gives metastable [Fe(IV)(O)(N3Py(amide)SR)](2+) (2), containing a sulfide ligand and a single amide H-bond donor in proximity to the terminal o...

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Main Authors: Widger, Leland R., Davies, Casey G., Yang, Tzuhsiung, Siegler, Maxime A., Troeppner, Oliver, Jameson, Guy N. L., Ivanović-Burmazović, Ivana, Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4004223/
https://ncbi.nlm.nih.gov/pubmed/24471779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410240c
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