Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations

The synthesis and reactivity of a series of mononuclear nonheme iron complexes that carry out intramolecular aromatic C–F hydroxylation reactions is reported. The key intermediate prior to C–F hydroxylation, [Fe(IV)(O)-(N4Py(2Ar(1)))](BF(4))(2) (1-O, Ar(1) = −2,6-difluorophenyl), was characterized b...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Sahu, Sumit, Zhang, Bo, Pollock, Christopher J., Dürr, Maximilian, Davies, Casey G., Confer, Alex M., Ivanović-Burmazović, Ivana, Siegler, Maxime A., Jameson, Guy N. L., Krebs, Carsten, Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5628738/
https://ncbi.nlm.nih.gov/pubmed/27656776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03346
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