Direct Observation of a Nonheme Iron(IV)–Oxo Complex That Mediates Aromatic C–F Hydroxylation

[Image: see text] The synthesis of a pentadentate ligand with strategically designed fluorinated arene groups in the second coordination sphere of a nonheme iron center is reported. The oxidatively resistant fluorine substituents allow for the trapping and characterization of an Fe(IV)(O) complex at...

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Главные авторы: Sahu, Sumit, Quesne, Matthew G., Davies, Casey G., Dürr, Maximilian, Ivanović-Burmazović, Ivana, Siegler, Maxime A., Jameson, Guy N. L., de Visser, Sam P., Goldberg, David P.
Формат: Artigo
Язык:Inglês
Опубликовано: American Chemical Society 2014
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC4183621/
https://ncbi.nlm.nih.gov/pubmed/25246108
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja507346t
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