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Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
[Image: see text] The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C(6)F(5))(3) leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C(6)F(5))(3), reacts with ArO–H substrates via formal hydrogen...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American
Chemical Society
2014
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4066901/ https://ncbi.nlm.nih.gov/pubmed/24873989 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic500901y |
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