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A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds

High-valent metal-hydroxide species are invoked as critical intermediates in both catalytic, metal-mediated O(2) activation (e.g. by Fe porphyrin in Cytochrome P450) and O(2) production (e.g. by the Mn cluster in Photosystem II). However, well-characterized mononuclear M(IV)(OH) complexes remain a r...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Zaragoza, Jan Paulo T., Siegler, Maxime A., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6066600/
https://ncbi.nlm.nih.gov/pubmed/29542921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00350
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