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A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
High-valent metal-hydroxide species are invoked as critical intermediates in both catalytic, metal-mediated O(2) activation (e.g. by Fe porphyrin in Cytochrome P450) and O(2) production (e.g. by the Mn cluster in Photosystem II). However, well-characterized mononuclear M(IV)(OH) complexes remain a r...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6066600/ https://ncbi.nlm.nih.gov/pubmed/29542921 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00350 |
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