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The Hydrogen Atom Transfer Reactivity of a Porphyrinoid Cobalt Superoxide Complex
The H-atom transfer (HAT) reactivity of a corrolazine cobalt superoxide with weak O–H and N–H substrates has been demonstrated. Kinetic analysis shows relatively fast rates of HAT with diphenylhydrazine (DPH). A kinetic isotope effect (KIE) and Eyring activation parameters are consistent with an HAT...
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| 發表在: | Chem Commun (Camb) |
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| Main Authors: | , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6375684/ https://ncbi.nlm.nih.gov/pubmed/30608073 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc08453j |
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