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The Hydrogen Atom Transfer Reactivity of a Porphyrinoid Cobalt Superoxide Complex
The H-atom transfer (HAT) reactivity of a corrolazine cobalt superoxide with weak O–H and N–H substrates has been demonstrated. Kinetic analysis shows relatively fast rates of HAT with diphenylhydrazine (DPH). A kinetic isotope effect (KIE) and Eyring activation parameters are consistent with an HAT...
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| Publicat a: | Chem Commun (Camb) |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6375684/ https://ncbi.nlm.nih.gov/pubmed/30608073 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc08453j |
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