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High-Valent Manganese-Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C−H Bond Cleavage
The addition of Lewis or Brönsted acids (LA = Zn(OTf)(2), B(C(6)F(5))(3), HBAr(F), TFA) to the high-valent manganese—oxo complex Mn(V)(O)(TBP(8)Cz) results in the stabilization of a valence tautomer Mn(IV)(O-LA)(TBP(8)Cz(•+)). The Zn(II) and B(C(6)F(5))(3) complexes were characterized by manganese K...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5228481/ https://ncbi.nlm.nih.gov/pubmed/27689821 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02109 |
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