Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}(7) Complex with Dioxygen

The nonheme iron complex, [Fe(NO)(N3PyS)]BF(4), is a rare example of an {FeNO}(7) species that exhibits spin-crossover behavior. The comparison of X-ray crystallographic studies at low and high temperatures and variable-temperature magnetic susceptibility measurements show that a low-spin S = 1/2 gr...

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Vydáno v:J Am Chem Soc
Hlavní autoři: McQuilken, Alison C., Matsumura, Hirotoshi, Dürr, Maximilian, Confer, Alex M., Sheckelton, John P., Siegler, Maxime A., McQueen, Tyrel M., Ivanović-Burmazović, Ivana, Moënne-Loccoz, Pierre, Goldberg, David P.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5502531/
https://ncbi.nlm.nih.gov/pubmed/26919583
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12741
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