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Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}(7) Complex with Dioxygen
The nonheme iron complex, [Fe(NO)(N3PyS)]BF(4), is a rare example of an {FeNO}(7) species that exhibits spin-crossover behavior. The comparison of X-ray crystallographic studies at low and high temperatures and variable-temperature magnetic susceptibility measurements show that a low-spin S = 1/2 gr...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5502531/ https://ncbi.nlm.nih.gov/pubmed/26919583 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12741 |
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