Secondary Coordination Sphere Influence on the Reactivity of Nonheme Iron(II) Complexes: An Experimental and DFT Approach

[Image: see text] The new biomimetic ligands N4Py(2Ph) (1) and N4Py(2Ph,amide) (2) were synthesized and yield the iron(II) complexes [Fe(II)(N4Py(2Ph))(NCCH(3))](BF(4))(2) (3) and [Fe(II)(N4Py(2Ph,amide))](BF(4))(2) (5). Controlled orientation of the Ph substituents in 3 leads to facile triplet spin...

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Main Authors: Sahu, Sumit, Widger, Leland R., Quesne, Matthew G., de Visser, Sam P., Matsumura, Hirotoshi, Moënne-Loccoz, Pierre, Siegler, Maxime A., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3746373/
https://ncbi.nlm.nih.gov/pubmed/23834409
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402688t
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