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Secondary Coordination Sphere Influence on the Reactivity of Nonheme Iron(II) Complexes: An Experimental and DFT Approach
[Image: see text] The new biomimetic ligands N4Py(2Ph) (1) and N4Py(2Ph,amide) (2) were synthesized and yield the iron(II) complexes [Fe(II)(N4Py(2Ph))(NCCH(3))](BF(4))(2) (3) and [Fe(II)(N4Py(2Ph,amide))](BF(4))(2) (5). Controlled orientation of the Ph substituents in 3 leads to facile triplet spin...
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| Autori principali: | , , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2013
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3746373/ https://ncbi.nlm.nih.gov/pubmed/23834409 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402688t |
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