Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere()

The non-heme iron complexes, [Fe(II)(N3PySR)(CH(3)CN)](BF(4))(2) (1) and [Fe(II)(N3Py(amide)SR)](BF(4))(2) (2), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Widger, Leland R., Jiang, Yunbo, McQuilken, Alison C., Yang, Tzuhsiung, Siegler, Maxime A., Matsumura, Hirotoshi, Moënne-Loccoz, Pierre, Kumar, Devesh, de Visser, Sam P., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4319814/
https://ncbi.nlm.nih.gov/pubmed/24705907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt00281d
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