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Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N(4)S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes
The known iron(II) complex [Fe(II)(LN(3)S)(OTf)] (1) was used as starting material to prepare the new biomimetic (N(4)S(thiolate)) iron(II) complexes [Fe(II)(LN(3)S)(py)](OTf) (2) and [Fe(II)(LN(3)S)(DMAP)](OTf) (3), where LN(3)S is a tetradentate bis(imino)pyridine (BIP) derivative with a covalentl...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3827697/ https://ncbi.nlm.nih.gov/pubmed/23992096 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4013558 |
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