Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N(4)S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes

The known iron(II) complex [Fe(II)(LN(3)S)(OTf)] (1) was used as starting material to prepare the new biomimetic (N(4)S(thiolate)) iron(II) complexes [Fe(II)(LN(3)S)(py)](OTf) (2) and [Fe(II)(LN(3)S)(DMAP)](OTf) (3), where LN(3)S is a tetradentate bis(imino)pyridine (BIP) derivative with a covalentl...

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Main Authors: Widger, Leland R., Jiang, Yunbo, Siegler, Maxime, Kumar, Devesh, Latifi, Reza, de Visser, Sam P., Jameson, Guy N.L., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3827697/
https://ncbi.nlm.nih.gov/pubmed/23992096
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4013558
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