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O(2) Activation by Bis(imino)pyridine Iron(II)-Thiolate Complexes
The new iron(II)-thiolate complexes [((iPr)BIP)Fe(II)(SPh)(Cl)] (1) and [((iPr)BIP)Fe(II)(SPh)(OTf)] (2) (BIP = bis(iminopyridine)) were prepared as models for cysteine dioxygenase (CDO), which converts Cys to Cys-SO(2)H at a (His)(3)Fe(II) center. Reaction of 1 and 2 with O(2) leads to Fe-oxygenati...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3224977/ https://ncbi.nlm.nih.gov/pubmed/21207980 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja109923a |
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