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Iron(II)-Thiolate S-Oxygenation by O(2): Synthetic Models of Cysteine Dioxygenase
[Image: see text] The synthesis of structural and functional models of the active site of the non-heme iron enzyme cysteine dioxygenase (CDO) is reported. A bis(imino)pyridine ligand scaffold was employed to synthesize a mononuclear ferrous complex, Fe(II)(LN(3)S)(OTf) (1), which contains 3 neutral...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2938176/ https://ncbi.nlm.nih.gov/pubmed/20712312 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105591q |
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