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Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

There has been considerable interest in hydrogen atom transfer (HAT) reactions mediated by metal/oxygen species because of their central role in metalloenzyme function as well as synthetic catalysts. This Account focuses on our progress in synthesizing high-valent metal–oxo and metal–hydroxo porphyr...

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Dettagli Bibliografici
Pubblicato in:Acc Chem Res
Autori principali: Sacramento, Jireh Joy D., Goldberg, David P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6676912/
https://ncbi.nlm.nih.gov/pubmed/30403479
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.8b00414
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