Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

A mononuclear Cr(v)–oxo complex, [Cr(V)(O)(6-COO(–)-tpa)](BF(4))(2) (1; 6-COO(–)-tpa = N,N-bis(2-pyridylmethyl)-N-(6-carboxylato-2-pyridylmethyl)amine) was prepared through the reaction of a Cr(iii) precursor complex with iodosylbenzene as an oxidant. Characterization of 1 was achieved using ESI-MS...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Kotani, Hiroaki, Kaida, Suzue, Ishizuka, Tomoya, Sakaguchi, Miyuki, Ogura, Takashi, Shiota, Yoshihito, Yoshizawa, Kazunari, Kojima, Takahiko
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2015
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811151/
https://ncbi.nlm.nih.gov/pubmed/29560181
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02285h
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!

Ähnliche Einträge