Mn(IV)-oxo Complex of a Bis(benzimidazolyl)-containing N5 Ligand Reveals Different Reactivity Trends for Mn(IV)-oxo than Fe(IV)-oxo Species

Using the pentadentate ligand (N-bis(1-methyl-2-benzimidazolyl)methyl-N-(bis-2-pyridylmethyl)amine, 2pyN2B), presenting two pyridyl and two (N-methyl)benzimidazolyl donor moieties in addition to a central tertiary amine, new Mn(II) and Mn(IV)-oxo complexes were generated and characterized. The [Mn(I...

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Publicado no:Dalton Trans
Main Authors: Denler, Melissa C., Massie, Allyssa A., Singh, Reena, Stewart-Jones, Eleanor, Sinha, Arup, Day, Victor W., Nordlander, Ebbe, Jackson, Timothy A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6487477/
https://ncbi.nlm.nih.gov/pubmed/30916103
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9dt00308h
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