Equatorial Ligand Perturbations Influence the Reactivity of Mn(IV)-Oxo Complexes

Manganese(IV)-oxo complexes are often invoked as intermediates in Mn-catalyzed C-H bond activation reactions. While many synthetic Mn(IV)-oxo species are mild oxidants, other members of this class can attack strong C-H bonds. The basis for these reactivity differences is not well understood. Here we...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Massie, Allyssa A., Denler, Melissa C., Cardoso, Luísa Thiara, Walker, Ashlie N., Hossain, Md. Kamal, Day, Victor W., Nordlander, Ebbe, Jackson, Timothy A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5579827/
https://ncbi.nlm.nih.gov/pubmed/28300349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612309
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