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Equatorial Ligand Perturbations Influence the Reactivity of Mn(IV)-Oxo Complexes
Manganese(IV)-oxo complexes are often invoked as intermediates in Mn-catalyzed C-H bond activation reactions. While many synthetic Mn(IV)-oxo species are mild oxidants, other members of this class can attack strong C-H bonds. The basis for these reactivity differences is not well understood. Here we...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | Angew Chem Int Ed Engl |
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| Κύριοι συγγραφείς: | , , , , , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2017
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5579827/ https://ncbi.nlm.nih.gov/pubmed/28300349 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612309 |
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