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Concerted Proton-Electron Transfer Reactions of Manganese-Hydroxo and Manganese-Oxo Complexes
The enzymes manganese superoxide dismutase and manganese lipoxygenase use Mn(III)-hydroxo centres to mediate proton-coupled electron transfer (PCET) reactions with substrate. As manganese is earth-abundant and inexpensive, manganese catalysts are of interest for synthetic applications. Recent years...
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| Veröffentlicht in: | Chem Commun (Camb) |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7429365/ https://ncbi.nlm.nih.gov/pubmed/32578605 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc01201g |
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