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Concerted Proton-Electron Transfer Reactions of Manganese-Hydroxo and Manganese-Oxo Complexes

The enzymes manganese superoxide dismutase and manganese lipoxygenase use Mn(III)-hydroxo centres to mediate proton-coupled electron transfer (PCET) reactions with substrate. As manganese is earth-abundant and inexpensive, manganese catalysts are of interest for synthetic applications. Recent years...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Mayfield, Jaycee R., Grotemeyer, Elizabeth N., Jackson, Timothy A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7429365/
https://ncbi.nlm.nih.gov/pubmed/32578605
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc01201g
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