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Concerted proton-coupled electron transfers in aquo/hydroxo/oxo metal complexes: Electrochemistry of [Os(II)(bpy)(2)py(OH(2))](2+) in water
Kinetic analysis of the successive oxidative cyclic voltammetric responses of [Os(II)(bpy)(2)py(OH(2))](2+) in buffered water, together with determination of H/D isotope effects, has allowed the determination of the mechanisms of the successive proton-coupled electron transfers that convert the Os(I...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2715510/ https://ncbi.nlm.nih.gov/pubmed/19584254 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0905020106 |
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