Concerted proton-coupled electron transfers in aquo/hydroxo/oxo metal complexes: Electrochemistry of [Os(II)(bpy)(2)py(OH(2))](2+) in water

Kinetic analysis of the successive oxidative cyclic voltammetric responses of [Os(II)(bpy)(2)py(OH(2))](2+) in buffered water, together with determination of H/D isotope effects, has allowed the determination of the mechanisms of the successive proton-coupled electron transfers that convert the Os(I...

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Bibliografiska uppgifter
Huvudupphovsmän: Costentin, Cyrille, Robert, Marc, Savéant, Jean-Michel, Teillout, Anne-Lucie
Materialtyp: Artigo
Språk:Inglês
Publicerad: National Academy of Sciences 2009
Ämnen:
Physical Sciences
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2715510/
https://ncbi.nlm.nih.gov/pubmed/19584254
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0905020106
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