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Concerted heavy-atom bond cleavage and proton and electron transfers illustrated by proton-assisted reductive cleavage of an O–O bond

Electron transfer may be concerted with proton transfer. It may also be concerted with the cleavage of a bond between heavy atoms. All three events may also be concerted. A model is presented to analyze the kinetics of these all-concerted reactions for homogeneous or electrochemical reduction or oxi...

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Bibliografiska uppgifter
Huvudupphovsmän: Costentin, Cyrille, Hajj, Viviane, Robert, Marc, Savéant, Jean-Michel, Tard, Cédric
Materialtyp: Artigo
Språk:Inglês
Publicerad: National Academy of Sciences 2011
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3102404/
https://ncbi.nlm.nih.gov/pubmed/21551101
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1104952108
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