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Concerted proton-electron transfer reactions in the Marcus inverted region
Electron transfer reactions slow down when they become very thermodynamically favorable, a counterintuitive interplay of kinetics and thermodynamics termed the inverted region in Marcus theory. Here we report inverted region behavior for proton-coupled electron transfer (PCET). Photochemical studies...
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| Publicado no: | Science |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6681808/ https://ncbi.nlm.nih.gov/pubmed/30975771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaw4675 |
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