Concerted proton-electron transfer reactions in the Marcus inverted region

Electron transfer reactions slow down when they become very thermodynamically favorable, a counterintuitive interplay of kinetics and thermodynamics termed the inverted region in Marcus theory. Here we report inverted region behavior for proton-coupled electron transfer (PCET). Photochemical studies...

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Gepubliceerd in:Science
Hoofdauteurs: Parada, Giovanny A., Goldsmith, Zachary K., Kolmar, Scott, Rimgard, Belinda Pettersson, Mercado, Brandon Q., Hammarström, Leif, Hammes-Schiffer, Sharon, Mayer, James M.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2019
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Article
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6681808/
https://ncbi.nlm.nih.gov/pubmed/30975771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaw4675
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