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Driving force dependence of rates for nonadiabatic proton and proton-coupled electron transfer: Conditions for inverted region behavior
The driving force dependence of the rate constants for nonadiabatic electron transfer (ET), proton transfer (PT), and proton-coupled electron transfer (PCET) reactions are examined. Inverted region behavior, where the rate constant decreases as the reaction becomes more exoergic (i.e., as ΔG(0) beco...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2783471/ https://ncbi.nlm.nih.gov/pubmed/19795899 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp907808t |
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