Concerted proton-electron transfer reactions in the Marcus inverted region

Electron transfer reactions slow down when they become very thermodynamically favorable, a counterintuitive interplay of kinetics and thermodynamics termed the inverted region in Marcus theory. Here we report inverted region behavior for proton-coupled electron transfer (PCET). Photochemical studies...

Descripción completa

Guardado en:
Detalles Bibliográficos
Publicado en:Science
Autores principales: Parada, Giovanny A., Goldsmith, Zachary K., Kolmar, Scott, Rimgard, Belinda Pettersson, Mercado, Brandon Q., Hammarström, Leif, Hammes-Schiffer, Sharon, Mayer, James M.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2019
Materias:
Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6681808/
https://ncbi.nlm.nih.gov/pubmed/30975771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaw4675
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!

Ejemplares similares