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Separating Proton and Electron Transfer Effects in Three-Component Concerted PCET Reactions
Multiple-site concerted proton electron transfer (MS-CPET) reactions were studied in a three-component system. 1-hydroxy-2,2,6,6-tetramethylpiperidine (TEMPOH) was oxidized to the stable radical TEMPO by electron transfer to ferrocenium oxidants coupled to proton transfer to various pyridine bases....
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5812448/ https://ncbi.nlm.nih.gov/pubmed/28671470 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03562 |
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