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Probing Quantum and Dynamic Effects in Concerted Proton-Electron Transfer Reactions of Phenol-Base Compounds
The oxidation of three phenols which contain an intramolecular hydrogen bond to a pendent pyridine or amine group has been shown, in a previous experimental study, to undergo concerted proton electron transfer (CPET). In this reaction, the electron is transferred to an outer-sphere oxidant and the p...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2011
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3974916/ https://ncbi.nlm.nih.gov/pubmed/22148459 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp2091736 |
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