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Multiple-Site Concerted Proton-Electron Transfer Reactions of Hydrogen-Bonded Phenols are Non-adiabatic and Well Described by Semi-Classical Marcus Theory
Photo-oxidations of hydrogen-bonded phenols using excited state polyarenes are described, to derive fundamental understanding of multiple-site concerted proton-electron transfer reactions (MS-CPET). Experiments have examined phenol-bases having −CPh(2)NH(2), −Py, and −CH(2)Py groups ortho to the phe...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2012
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3476473/ https://ncbi.nlm.nih.gov/pubmed/22974135 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305668h |
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