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Multiple-Site Concerted Proton-Electron Transfer Reactions of Hydrogen-Bonded Phenols are Non-adiabatic and Well Described by Semi-Classical Marcus Theory

Photo-oxidations of hydrogen-bonded phenols using excited state polyarenes are described, to derive fundamental understanding of multiple-site concerted proton-electron transfer reactions (MS-CPET). Experiments have examined phenol-bases having −CPh(2)NH(2), −Py, and −CH(2)Py groups ortho to the phe...

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Hlavní autoři: Schrauben, Joel N., Cattaneo, Mauricio, Day, Thomas C., Tenderholt, Adam L., Mayer, James M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3476473/
https://ncbi.nlm.nih.gov/pubmed/22974135
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305668h
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