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Concerted Proton-Electron Transfer in the Oxidation of Hydrogen-Bonded Phenols
Three phenols with pendant, hydrogen-bonded bases (HOAr-B) have been oxidized in MeCN with various one-electron oxidants. The bases are a primary amine (–CPh(2)NH(2)), an imidazole, and a pyridine. The product of chemical and quasi-reversible electrochemical oxidations in each case is the phenoxyl r...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2006
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2518092/ https://ncbi.nlm.nih.gov/pubmed/16669677 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja054167+ |
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