Concerted Proton-Electron Transfer in the Oxidation of Hydrogen-Bonded Phenols

Three phenols with pendant, hydrogen-bonded bases (HOAr-B) have been oxidized in MeCN with various one-electron oxidants. The bases are a primary amine (–CPh(2)NH(2)), an imidazole, and a pyridine. The product of chemical and quasi-reversible electrochemical oxidations in each case is the phenoxyl r...

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Main Authors: Rhile, Ian J., Markle, Todd F., Nagao, Hirotaka, DiPasquale, Antonio G., Lam, Oahn P., Lockwood, Mark A., Rotter, Katrina, Mayer, James M.
格式: Artigo
語言:Inglês
出版: 2006
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2518092/
https://ncbi.nlm.nih.gov/pubmed/16669677
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja054167+
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