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Effect of Basic Site Substituents on Concerted Proton-Electron Transfer in Hydrogen Bonded-Pyridyl Phenols

Separated concerted proton-electron transfer (sCPET) reactions of two series of phenols with pendent substituted pyridyl moieties are described. The pyridine is either attached directly to the phenol (HOAr-pyX) or connected through a methylene linker (HOArCH(2)pyX) (X = 4-NO(2), 5-CF(3), 4-CH(3), 4-...

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Detalhes bibliográficos
Main Authors: Markle, Todd F., Tronic, Tristan A., DiPasquale, Antonio G., Kaminsky, Werner, Mayer, James M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3926939/
https://ncbi.nlm.nih.gov/pubmed/23176252
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp311388n
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