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Probing Quantum and Dynamic Effects in Concerted Proton-Electron Transfer Reactions of Phenol-Base Compounds

The oxidation of three phenols which contain an intramolecular hydrogen bond to a pendent pyridine or amine group has been shown, in a previous experimental study, to undergo concerted proton electron transfer (CPET). In this reaction, the electron is transferred to an outer-sphere oxidant and the p...

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Autori principali: Markle, Todd F., Tenderholt, Adam L., Mayer, James M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3974916/
https://ncbi.nlm.nih.gov/pubmed/22148459
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp2091736
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