Carregant...
Surprisingly Long-Lived Ascorbyl Radicals in Acetonitrile: Concerted Proton-Electron Transfer Reactions and Thermochemistry
Proton-coupled electron transfer (PCET) reactions and thermochemistry of 5,6-isopropylidene ascorbate (iAscH(−)) have been examined in acetonitrile solvent.iAscH(−) is oxidized by 2,4,6-(t)Bu(3)C(6)H(2)O(•) and by excess TEMPO(•) to give the corresponding 5,6-isopropylidene ascorbyl radical anion (i...
Guardat en:
| Autors principals: | , |
|---|---|
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
|
| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2556879/ https://ncbi.nlm.nih.gov/pubmed/18505256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802055t |
| Etiquetes: |
Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!
|