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Surprisingly Long-Lived Ascorbyl Radicals in Acetonitrile: Concerted Proton-Electron Transfer Reactions and Thermochemistry
Proton-coupled electron transfer (PCET) reactions and thermochemistry of 5,6-isopropylidene ascorbate (iAscH(−)) have been examined in acetonitrile solvent.iAscH(−) is oxidized by 2,4,6-(t)Bu(3)C(6)H(2)O(•) and by excess TEMPO(•) to give the corresponding 5,6-isopropylidene ascorbyl radical anion (i...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2556879/ https://ncbi.nlm.nih.gov/pubmed/18505256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802055t |
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