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Cu(I)/O(2) Chemistry Using a β-Diketiminate Supporting Ligand Derived from N,N-Dimethylhydrazine: A [Cu(3)O(2)](3+) Complex with Novel Reactivity

A Cu(I) complex, LCu(CH(3)CN), was prepared and characterized, where L(−) is a sterically unencumbered β-diketiminate ligand, the deprotonated version of 4-(2,2-dimethylhydrazino)dimethylhydrazone-3-penten-2-one (LH). Analysis of FTIR spectra of the products of the reaction of LCu(CH(3)CN) with CO i...

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Detalhes bibliográficos
Main Authors: Gupta, Aalo K., Tolman, William B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3278800/
https://ncbi.nlm.nih.gov/pubmed/22268598
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic202214c
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